[Pd(dmpz)(2)(Hdmpz)(2)(2)] (Hdmpz = 3,5-dimethylpyrazole) reacts with COS, both in solution and in the solid state, affording [PdSC(O)dmpz(2)] and [Pd(dmpz)(2)(Hdmpz)(2)2]. COS, respectively; the structure of the latter is determined by ab initio methods from conventional X-ray powder diffraction data only.
COS TRAPPING BY PALLADIUM PYRAZOLATES - ADDITION VS CLATHRATION / N. Masciocchi, M. Moret, A. Sironi, G. A. Ardizzoia, S. Cenini, G. Lamonica. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :19(1995), pp. 1955-1956.
COS TRAPPING BY PALLADIUM PYRAZOLATES - ADDITION VS CLATHRATION
A. Sironi;S. CeniniPenultimo
;
1995
Abstract
[Pd(dmpz)(2)(Hdmpz)(2)(2)] (Hdmpz = 3,5-dimethylpyrazole) reacts with COS, both in solution and in the solid state, affording [PdSC(O)dmpz(2)] and [Pd(dmpz)(2)(Hdmpz)(2)2]. COS, respectively; the structure of the latter is determined by ab initio methods from conventional X-ray powder diffraction data only.File in questo prodotto:
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