The novel anion [Re 3H 3(CO) 9(μ 3-SBu t)] -, obtained by reaction of [Re 3H 4(CO) 10] - with t-butyl mercaptan, has been characterized by IR, NMR and X-ray diffraction studies. It contains an equilateral Re 3 triangle (mean ReRe 3.091 Å), with nine terminal carbonyl groups, three for each metal atom, and a triply-bridging thiolate ligand (mean ReS 2.393 Å). The three hydrides are bridging on the edges of the triangle of metal atoms. © 1982.
Reaction of the unsaturated anion [Re 3H 4(CO) 10] - with mercaptans. Synthesis and X-ray Characterization of the anion [ Re 3H 3 (CO) 9(μ 3-SBu t)] / R. Bonfichi, G. Ciani, G. D'Alfonso, P. Romiti, A. Sironi. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 231:2(1982), pp. c35-c35-c37.
Reaction of the unsaturated anion [Re 3H 4(CO) 10] - with mercaptans. Synthesis and X-ray Characterization of the anion [ Re 3H 3 (CO) 9(μ 3-SBu t)]
G. CianiSecondo
;G. D'Alfonso;A. SironiUltimo
1982
Abstract
The novel anion [Re 3H 3(CO) 9(μ 3-SBu t)] -, obtained by reaction of [Re 3H 4(CO) 10] - with t-butyl mercaptan, has been characterized by IR, NMR and X-ray diffraction studies. It contains an equilateral Re 3 triangle (mean ReRe 3.091 Å), with nine terminal carbonyl groups, three for each metal atom, and a triply-bridging thiolate ligand (mean ReS 2.393 Å). The three hydrides are bridging on the edges of the triangle of metal atoms. © 1982.Pubblicazioni consigliate
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