Oxidation of sulphides by in situ generated dioxiranes in buffered (pH 7.5) aqueous solutions, using bovine serum albumin (BSA) as a chiral auxiliary, affords the corresponding sulphoxides in up to 89% enantiomeric excess (e.e.).
Enantioselective oxidation of sulphides by dioxiranes in the presence of bovine serum albumin / S. Colonna, N. Gaggero. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 30:45(1989), pp. 6233-6236.
Enantioselective oxidation of sulphides by dioxiranes in the presence of bovine serum albumin
S. ColonnaPrimo
;N. GaggeroUltimo
1989
Abstract
Oxidation of sulphides by in situ generated dioxiranes in buffered (pH 7.5) aqueous solutions, using bovine serum albumin (BSA) as a chiral auxiliary, affords the corresponding sulphoxides in up to 89% enantiomeric excess (e.e.).
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