The unprecedented formation, in the course of the allene photoaddition to 18-benzyloxy-8(9)-podocarpen-14-one, of a by-product, due to a novel type of intramolecular hydrogen abstraction by the biradical intermediate, is described.
UNPRECEDENTED OUTCOME OF THE ALLENE PHOTOADDITION TO A FUSED ALPHA,BETA-UNSATURATED KETONE / M. BERETTONI, F. COCCHI, R. BETTOLO, L. DIMIRABELLO, S. ROMEO. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 34:4(1992), pp. 715-716.
UNPRECEDENTED OUTCOME OF THE ALLENE PHOTOADDITION TO A FUSED ALPHA,BETA-UNSATURATED KETONE
S. ROMEOUltimo
1992
Abstract
The unprecedented formation, in the course of the allene photoaddition to 18-benzyloxy-8(9)-podocarpen-14-one, of a by-product, due to a novel type of intramolecular hydrogen abstraction by the biradical intermediate, is described.
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