Reaction of the neutral hexaosmium cluster Os6(CO)18 with excess of pyridine (py) gives the pentanuclear dianion [Os 5(CO)15]2- together with small amounts of a neutral hexanuclear cluster Os6(CO)17(py)2 (1); X-ray analysis shows that (1) exhibits an unusual type of metal-carbonyl linkage.
The synthesis and x-ray structure analysis of Os6(CO) 17(NC5H5)2: A cluster compound with an unusual mode of metal-CO bonding / B. F. G. Johnson, J. Lewis, M. McPartlin, M. A. Pearsall, A. Sironi. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :16(1984), pp. 1089-1090.
The synthesis and x-ray structure analysis of Os6(CO) 17(NC5H5)2: A cluster compound with an unusual mode of metal-CO bonding
A. SironiUltimo
1984
Abstract
Reaction of the neutral hexaosmium cluster Os6(CO)18 with excess of pyridine (py) gives the pentanuclear dianion [Os 5(CO)15]2- together with small amounts of a neutral hexanuclear cluster Os6(CO)17(py)2 (1); X-ray analysis shows that (1) exhibits an unusual type of metal-carbonyl linkage.
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
