Reaction of anodically generated thiocyanogen (NaSCN, LiClO4, MeCN, Pt, 0.9V vs SCE) with 3-alkylsubstituted indoles results preferentially in isothiocyanation at the indole 2-position rather than in the expected thiocyanation.
SELECTIVITY IN THE THIOCYANATION OF 3-ALKYLINDOLES - AN UNEXPECTEDLY EASY ACCESS TO 2-ISOTHIOCYANO DERIVATIVES / G. PALMISANO, E. BRENNA, B. DANIELI, G. LESMA, B. VODOPIVEC, G. FIORI. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 31:49(1990), pp. 7229-7232.
SELECTIVITY IN THE THIOCYANATION OF 3-ALKYLINDOLES - AN UNEXPECTEDLY EASY ACCESS TO 2-ISOTHIOCYANO DERIVATIVES
B. DANIELI;G. LESMA;G. FIORIUltimo
1990
Abstract
Reaction of anodically generated thiocyanogen (NaSCN, LiClO4, MeCN, Pt, 0.9V vs SCE) with 3-alkylsubstituted indoles results preferentially in isothiocyanation at the indole 2-position rather than in the expected thiocyanation.
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