N-Substituted cyclic iminium salts are conveniently reduced to the corresponding tertiary amines in good yields by reaction with tributylstannane in methanol at room temperature. A variety of functional groups (such as ketonic groups) present in the molecule are not affected under these conditions.
A Mild and Chemoselective Reduction of Cyclic Iminium Salts / G. Palmisano, G. Lesma, M. Nali, B. Rindone, S. Tollari. - In: SYNTHESIS. - ISSN 0039-7881. - :11(1985), pp. 1072-1074.
A Mild and Chemoselective Reduction of Cyclic Iminium Salts
G. LesmaSecondo
;
1985
Abstract
N-Substituted cyclic iminium salts are conveniently reduced to the corresponding tertiary amines in good yields by reaction with tributylstannane in methanol at room temperature. A variety of functional groups (such as ketonic groups) present in the molecule are not affected under these conditions.
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
