A C-glucoside ofcholic acid was synthesized by the introduction of an acetyl group at position 3α and direct one-pot C-glucosidation using 2,3,4,6-tetra-O-benzyl-α-d-glucopyranosyl chloride.
SYNTHESIS OF 7-ALPHA,12-ALPHA-DIHYDROXY-3-ALPHA-[2-(BETA-D-GLUCOPYRANOSYL)ACETYL]-5-B ETA-CHOLAN-24-OIC ACID / P. ALLEVI, M. ANASTASIA, P. CIUFFREDA, A. FIECCHI, A. SANVITO. - In: STEROIDS. - ISSN 0039-128X. - 55:7(1990), pp. 303-307.
SYNTHESIS OF 7-ALPHA,12-ALPHA-DIHYDROXY-3-ALPHA-[2-(BETA-D-GLUCOPYRANOSYL)ACETYL]-5-B ETA-CHOLAN-24-OIC ACID
P. ALLEVIPrimo
;M. ANASTASIASecondo
;P. CIUFFREDA;
1990
Abstract
A C-glucoside ofcholic acid was synthesized by the introduction of an acetyl group at position 3α and direct one-pot C-glucosidation using 2,3,4,6-tetra-O-benzyl-α-d-glucopyranosyl chloride.
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