A route for the synthesis of α-C-glucosides of β-keto esters and ketones through the reaction of the corresponding enamines with 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl chloride activated by silver(I) trifluoromethanesulphonate is described.
AN EFFICACIOUS C-GLUCOSIDATION OF BETA-KETOESTERS AND KETONES VIA ENAMINES / P. ALLEVI, M. ANASTASIA, P. CIUFFREDA, A. FIECCHI, A. SCALA. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :1(1988), pp. 57-58.
AN EFFICACIOUS C-GLUCOSIDATION OF BETA-KETOESTERS AND KETONES VIA ENAMINES
P. ALLEVIPrimo
;M. ANASTASIASecondo
;P. CIUFFREDA;
1988
Abstract
A route for the synthesis of α-C-glucosides of β-keto esters and ketones through the reaction of the corresponding enamines with 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl chloride activated by silver(I) trifluoromethanesulphonate is described.
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