The synthesis of the new anions [H3Re3(CO)10]2- and [H3Re3(μ3-O)(CO)9]2-, obtained from [H4Re4(CO)15]2-, and their characterization by IR, NMR and X-ray analyses are reported; both species contain a triangular metal atom cluster and the former, which is electron deficient, contains a ReRe double bond. ca]To whom correspondence should be addressed. © 1976.
Synthesis and x-ray chracterization of the dianions trihydridodecacarbonyltrirhenate(2-)and trihydrido-μ3-oxoenneacarbonyltrirhenate(2-) / A. Bertolucci, M. Freni, P. Romiti, G. Ciani, A. Sironi, V. G. Albano. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 113:4(1976), pp. C61-C61-C64. [10.1016/S0022-328X(00)96153-9]
Synthesis and x-ray chracterization of the dianions trihydridodecacarbonyltrirhenate(2-)and trihydrido-μ3-oxoenneacarbonyltrirhenate(2-)
G. Ciani;A. SironiPenultimo
;
1976
Abstract
The synthesis of the new anions [H3Re3(CO)10]2- and [H3Re3(μ3-O)(CO)9]2-, obtained from [H4Re4(CO)15]2-, and their characterization by IR, NMR and X-ray analyses are reported; both species contain a triangular metal atom cluster and the former, which is electron deficient, contains a ReRe double bond. ca]To whom correspondence should be addressed. © 1976.
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