Initial thermoelectric power determinations were carried out on the molten systems (Cu, Ag)X, (X=Cl, Br, I) at 1000K. As for the employing of either copper or silver electrode thermocells, the choice was based on literature thermodynamic data. Comparison between ideal and actual behaviour allowed the authors to discover negative excess partial ionic entropies.
Thermoelectric power of the molten systems (Cu, Ag)X (X=Cl, Br, I) / A. Schiraldi, E. Pezzati. - In: ZEITSCHRIFT FÜR NATURFORSCHUNG. TEIL A, PHYSIK, PHYSIKALISCHE CHEMIE, KOSMOPHYSIK. - ISSN 0340-4811. - 33:1(1978 Jan), pp. 42-44. [10.1515/zna-1978-0109]
Thermoelectric power of the molten systems (Cu, Ag)X (X=Cl, Br, I)
A. SchiraldiPrimo
;
1978
Abstract
Initial thermoelectric power determinations were carried out on the molten systems (Cu, Ag)X, (X=Cl, Br, I) at 1000K. As for the employing of either copper or silver electrode thermocells, the choice was based on literature thermodynamic data. Comparison between ideal and actual behaviour allowed the authors to discover negative excess partial ionic entropies.
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