Three structural motifs have been obtained by using the novel building block trans-[RuCl2(pyz)4] with different silver salts: A two-dimensional network with an unprecedented double-honeycomb topology, a three-dimensional array with the rutile (6,3) structure, and an interesting tetragonal network with both Ru and Ag in octahedral environments, which can be related to the rock-salt topology (see picture).
Crystal engineering of mixed-metal Ru-Ag coordination networks by using the trans-[RuCl2(PYZ)(4)] (pyz = pyrazine) building block / L. Carlucci, G. Ciani, F. Porta, D.M. Proserpio, L. Santagostini. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - 41:11(2002), pp. 1907-1911. [10.1002/1521-3773(20020603)41:11<1907::AID-ANIE1907>3.0.CO;2-3]
Crystal engineering of mixed-metal Ru-Ag coordination networks by using the trans-[RuCl2(PYZ)(4)] (pyz = pyrazine) building block
L. Carlucci;G. Ciani;F. Porta;D.M. Proserpio;L. Santagostini
2002
Abstract
Three structural motifs have been obtained by using the novel building block trans-[RuCl2(pyz)4] with different silver salts: A two-dimensional network with an unprecedented double-honeycomb topology, a three-dimensional array with the rutile (6,3) structure, and an interesting tetragonal network with both Ru and Ag in octahedral environments, which can be related to the rock-salt topology (see picture).
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