Two novel silver(I) coordination polymers, [Ag(ppz)(2)](BF4) (1) and [Ag(pyz)(2)](PF6) (2) (ppz = piperazine, pyz = pyrazine), are prepared. Their crystal structures are found to contain markedly undulated 2D networks of distorted squares of Ag+ cations, in tetrahedral (1) and disphenoidal coordination geometries (2).
2D POLYMERIC SILVER(I) COMPLEXES CONSISTING OF MARKEDLY UNDULATED SHEETS OF SQUARES - X-RAY CRYSTAL-STRUCTURES OF [AG(PPZ)(2)](BF4) AND [AG(PYZ)(2)](PF6) (PPZ=PIPERAZINE, PYZ=PYRAZINE) / L. CARLUCCI, G. CIANI, D.M. PROSERPIO, A. SIRONI. - In: INORGANIC CHEMISTRY. - ISSN 0020-1669. - 34:22(1995), pp. 5698-5700. [10.1021/ic00126a048]
2D POLYMERIC SILVER(I) COMPLEXES CONSISTING OF MARKEDLY UNDULATED SHEETS OF SQUARES - X-RAY CRYSTAL-STRUCTURES OF [AG(PPZ)(2)](BF4) AND [AG(PYZ)(2)](PF6) (PPZ=PIPERAZINE, PYZ=PYRAZINE)
L. CarlucciPrimo
;G. CianiSecondo
;D.M. ProserpioPenultimo
;A. SironiUltimo
1995
Abstract
Two novel silver(I) coordination polymers, [Ag(ppz)(2)](BF4) (1) and [Ag(pyz)(2)](PF6) (2) (ppz = piperazine, pyz = pyrazine), are prepared. Their crystal structures are found to contain markedly undulated 2D networks of distorted squares of Ag+ cations, in tetrahedral (1) and disphenoidal coordination geometries (2).
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