A noteworthy three-dimensional framework, obtained by reacting the preformed molecular corner [Cu(2,2'-bipy)](2+) (with BF(4)(-) counter ions) and 1,2-bis(4-pyridyl)ethane (bpetha) in the presence of chlorides, contains molecular square units [Cu(2,2'-bipy)(bpetha)](4) that are linked via chloride bridges into a triconnected architecture of unprecedented topology.
Interlinked molecular squares with [Cu(2,2 '-bipy)](2+) corners generating a three-dimensional network of unprecedented topological type / L. Carlucci, G. Ciani, D.M. Proserpio, S. Rizzato. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - :13(2001), pp. 1198-1199.
Interlinked molecular squares with [Cu(2,2 '-bipy)](2+) corners generating a three-dimensional network of unprecedented topological type
L. CarlucciPrimo
;G. CianiSecondo
;D.M. ProserpioPenultimo
;S. RizzatoUltimo
2001
Abstract
A noteworthy three-dimensional framework, obtained by reacting the preformed molecular corner [Cu(2,2'-bipy)](2+) (with BF(4)(-) counter ions) and 1,2-bis(4-pyridyl)ethane (bpetha) in the presence of chlorides, contains molecular square units [Cu(2,2'-bipy)(bpetha)](4) that are linked via chloride bridges into a triconnected architecture of unprecedented topology.
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