The reaction of novel C2-symmetric bis-sulfinate esters derived from (R)-BINOL with Grignard reagents affords tert-butyl sulfoxides in ee up to 97%. The desired enantiomer can be generated at will by the proper selection of BINOL.
BINOL derived C2-symmetric bis-sulfinates as efficient sulfinyl transfer agents in the synthesis of tert-butyl sulfoxides / N. Gaggero, D.C.M. Albanese. - In: TETRAHEDRON. - ISSN 0040-4020. - 68:35(2012), pp. 7129-7132.
BINOL derived C2-symmetric bis-sulfinates as efficient sulfinyl transfer agents in the synthesis of tert-butyl sulfoxides
N. GaggeroPrimo
;D.C.M. AlbaneseUltimo
2012
Abstract
The reaction of novel C2-symmetric bis-sulfinate esters derived from (R)-BINOL with Grignard reagents affords tert-butyl sulfoxides in ee up to 97%. The desired enantiomer can be generated at will by the proper selection of BINOL.
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