The N-transacylation of secondary amides to their perfluorinated analogues with the possibility of subsequent conversion into a normal amide is reported (see scheme). This reaction occurs in the presence of a variety of functional groups that are labile to the hydrolysis conditions required by classical N-transacylation.
General and Chemoselective N-Transacylation of Secondary Amides by Means of Perfluorinated Anhydrides / P. Rota, P. Allevi, R. Colombo, M.L. Costa, M. Anastasia. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - 49:10(2010 Feb 09), pp. 1850-1853.
General and Chemoselective N-Transacylation of Secondary Amides by Means of Perfluorinated Anhydrides
P. RotaPrimo
;P. AlleviSecondo
;R. Colombo;M.L. CostaPenultimo
;M. AnastasiaUltimo
2010
Abstract
The N-transacylation of secondary amides to their perfluorinated analogues with the possibility of subsequent conversion into a normal amide is reported (see scheme). This reaction occurs in the presence of a variety of functional groups that are labile to the hydrolysis conditions required by classical N-transacylation.
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