Phosphorus acids are excellent promoters for the palladium-phenanthroline catalyzed corbonylation of 2,4-dinitrotoluene to 2,4-toluenedicarbamate. For the first time, all intermediate nitrocarbamates and aminocarbamates have been independently synthesized and their amount after every catalytic reaction precisely quantified.

Carbonylation of dinitrotoluene to dimethyl toluenedicarbamate; high efficiency of phosphorus acids as promoters for the palladium-phenanthroline catalytic system / M. Gasperini, F. Ragaini, C. Cazzaniga, S. Cenini. - In: ADVANCED SYNTHESIS & CATALYSIS. - ISSN 1615-4150. - 347:1(2005), pp. 105-120.

Carbonylation of dinitrotoluene to dimethyl toluenedicarbamate; high efficiency of phosphorus acids as promoters for the palladium-phenanthroline catalytic system

F. Ragaini
Secondo
;
S. Cenini
Ultimo
2005

Abstract

Phosphorus acids are excellent promoters for the palladium-phenanthroline catalyzed corbonylation of 2,4-dinitrotoluene to 2,4-toluenedicarbamate. For the first time, all intermediate nitrocarbamates and aminocarbamates have been independently synthesized and their amount after every catalytic reaction precisely quantified.
Settore CHIM/03 - Chimica Generale e Inorganica
2005
Article (author)
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/16399
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