The reductive coupling of the bridging phosphide and the adjacent sigma-alkynyl moieties in [Pt-2(mu-(PBu2)-Bu-t){mu,eta(1):eta(2)-C( Ph) CH2}(C=C - Ph)(CO)(P-t Bu2H)(Br)] is promoted by bromide abstraction and is reversed by adding (NBu4Br)-Bu-n.
Unprecedented reversible coupling of alkynyl and phosphide ligands on a dinuclear platinum framework / A. Albinati, V. Filippi, P. Leoni, L. Marchetti, M. Pasquali, V. Passarelli. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 2005:16(2005), pp. 2155-2157.
Unprecedented reversible coupling of alkynyl and phosphide ligands on a dinuclear platinum framework
A. AlbinatiPrimo
;
2005
Abstract
The reductive coupling of the bridging phosphide and the adjacent sigma-alkynyl moieties in [Pt-2(mu-(PBu2)-Bu-t){mu,eta(1):eta(2)-C( Ph) CH2}(C=C - Ph)(CO)(P-t Bu2H)(Br)] is promoted by bromide abstraction and is reversed by adding (NBu4Br)-Bu-n.
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