alpha- or beta-Galactofuranosyl (Gall) amides can be synthesized with high stereoselectivity by traceless Staudinger ligation starting from unprotected beta-galactofuranosyl azide or tetra-O-acetyl-beta-galactofuranosyl azide, respectively. The resulting Galf amides are hitherto unknown molecules, with interesting potential as inhibitors of mycobacterial growth.
Stereoselective synthesis of N-galactofuranosyl amides / F. Nisic, A. Bernardi. - In: CARBOHYDRATE RESEARCH. - ISSN 0008-6215. - 346:4(2011), pp. 465-471. [10.1016/j.carres.2010.12.020]
Stereoselective synthesis of N-galactofuranosyl amides
F. NisicPrimo
;A. BernardiUltimo
2011
Abstract
alpha- or beta-Galactofuranosyl (Gall) amides can be synthesized with high stereoselectivity by traceless Staudinger ligation starting from unprotected beta-galactofuranosyl azide or tetra-O-acetyl-beta-galactofuranosyl azide, respectively. The resulting Galf amides are hitherto unknown molecules, with interesting potential as inhibitors of mycobacterial growth.
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