Non-CsCl topologies for eight-connected solid-state materials have been observed for the first time in three networks based on lanthanide cations and 4,4-bipyridine-N,N-dioxide ligands. The structure of the {[Yb(L)4](CF3SO3)3} network is depicted.
Non-natural eight-connected solid-state materials: a new coordination chemistry / D. Long, R.J. Hill, A.J. Blake, N.R. Champness, P. Hubberstey, D.M. Proserpio, C. Wilson, M. Schröder. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - 43:14(2004), pp. 1851-1854. [10.1002/anie.200352625]
Non-natural eight-connected solid-state materials: a new coordination chemistry
D.M. Proserpio;
2004
Abstract
Non-CsCl topologies for eight-connected solid-state materials have been observed for the first time in three networks based on lanthanide cations and 4,4-bipyridine-N,N-dioxide ligands. The structure of the {[Yb(L)4](CF3SO3)3} network is depicted.
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