The reduction of nitro compounds to the corresponding amines is one of the most utilized catalytic processes in the fine and bulk chemical industry. The latest development of catalysts with cheap metals like Fe, Co, Ni, and Cu has led to their tremendous achievements over the last years prompting their greater application as "standard" catalysts. In this review, we will comprehensively discuss the use of homogeneous and heterogeneous catalysts based on non-noble 3d-metals for the reduction of nitro compounds using various reductants. The different systems will be revised considering both the catalytic performances and synthetic aspects highlighting also their advantages and disadvantages.
Reduction of nitro compounds using 3d-non-noble metal catalysts / D. Formenti, F. Ferretti, K. Scharnagl Florian, M. Beller. - In: CHEMICAL REVIEWS. - ISSN 0009-2665. - 119:4(2019 Feb 27), pp. 2611-2680.
Reduction of nitro compounds using 3d-non-noble metal catalysts
D. FormentiPrimo
Writing – Original Draft Preparation
;F. FerrettiSecondo
Writing – Original Draft Preparation
;
2019
Abstract
The reduction of nitro compounds to the corresponding amines is one of the most utilized catalytic processes in the fine and bulk chemical industry. The latest development of catalysts with cheap metals like Fe, Co, Ni, and Cu has led to their tremendous achievements over the last years prompting their greater application as "standard" catalysts. In this review, we will comprehensively discuss the use of homogeneous and heterogeneous catalysts based on non-noble 3d-metals for the reduction of nitro compounds using various reductants. The different systems will be revised considering both the catalytic performances and synthetic aspects highlighting also their advantages and disadvantages.File | Dimensione | Formato | |
---|---|---|---|
Nitroreduction - revised.pdf
Open Access dal 29/02/2020
Descrizione: Articolo principale
Tipologia:
Post-print, accepted manuscript ecc. (versione accettata dall'editore)
Dimensione
5.24 MB
Formato
Adobe PDF
|
5.24 MB | Adobe PDF | Visualizza/Apri |
acs.chemrev.8b00547-min.pdf
accesso riservato
Descrizione: Articolo principale
Tipologia:
Publisher's version/PDF
Dimensione
2.9 MB
Formato
Adobe PDF
|
2.9 MB | Adobe PDF | Visualizza/Apri Richiedi una copia |
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.