A new family of rare-earth polymeric framework RPF-4 has been obtained and its structure solved from an intrinsically triple twinned crystal. The framework formed by a H - O bond free rare-earth matrix, with the Ln atoms separated in two directions, makes them very promising materials for light-emitting diodes. The properties of the materials as heterogeneous catalysts are reported, too. IR spectroscopy suggests the presence of a peroxo complex that acts as active species in the oxidation reaction.
A rare-earth MOF series: Fascinating structure, efficient light emitters, and promising catalysts / F. Gandara, A. de Andres, B. Gomez-Lor, E. Gutierrez-Puebla, M. Iglesias, M.A. Monge, D.M. Proserpio, N. Snejko. - In: CRYSTAL GROWTH & DESIGN. - ISSN 1528-7483. - 8:2(2008), pp. 378-380.
A rare-earth MOF series: Fascinating structure, efficient light emitters, and promising catalysts
D.M. ProserpioPenultimo
;
2008
Abstract
A new family of rare-earth polymeric framework RPF-4 has been obtained and its structure solved from an intrinsically triple twinned crystal. The framework formed by a H - O bond free rare-earth matrix, with the Ln atoms separated in two directions, makes them very promising materials for light-emitting diodes. The properties of the materials as heterogeneous catalysts are reported, too. IR spectroscopy suggests the presence of a peroxo complex that acts as active species in the oxidation reaction.
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