A highly enantioselective rhodium-catalysed conjugate addition of phenylboronic acid to cyclic enones has been achieved using a dynamic library of chiral phosphorus ligands; the tropos/atropos nature of the ligands in the rhodium complex has been characterised via 31P-NMR.
Enantioselective Conjugate Addition of Phenylboronic Acid to Enones Catalyzed by a Chiral Tropos/Atropos Rhodium Complex at the Coalescence Temperature / C. Monti, C. Gennari, U. Piarulli. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 2005:42(2005), pp. 5281-5283.
Enantioselective Conjugate Addition of Phenylboronic Acid to Enones Catalyzed by a Chiral Tropos/Atropos Rhodium Complex at the Coalescence Temperature
C. MontiPrimo
;C. GennariSecondo
;
2005
Abstract
A highly enantioselective rhodium-catalysed conjugate addition of phenylboronic acid to cyclic enones has been achieved using a dynamic library of chiral phosphorus ligands; the tropos/atropos nature of the ligands in the rhodium complex has been characterised via 31P-NMR.
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