The inorganic-organic hybrid layered material of stoichiometry [DAMS+][Ag5I6-], characterized by a strong SHG activity, has been prepared mechanochemically by room-temperature ball-milling a mixture of AgI and [DAMS+][I-], eventually followed by a moderate heating. By means of electronic absorption spectra, XRPD, and second harmonic generation (SHG) experiments we proved that the intralayer ordering of the [DAMS+] nonlinear optical chromophores into J-aggregates precedes the interlayer one, on the whole producing, by a sequential process, the "macropolarity" responsible for the strong SHG. The mechanochemical approach was shown to be of general use, as it was successfully applied to the synthesis of the analogous [DAMS+][Cu5I6-], [DAZOP+][Ag5I6-], and [DAES+][Ag5I6-] materials.
Sequential Self-Organization of Silver(I) Layered Materials with Strong SHG by J Aggregation and Intercalation of Organic Nonlinear Optical Chromophores through Mechanochemical Synthesis / E. Cariati, R. Macchi, D. Roberto, R. Ugo, S. Galli, N. Masciocchi, A. Sironi. - In: CHEMISTRY OF MATERIALS. - ISSN 0897-4756. - 19:15(2007), pp. 3704-3711. [10.1021/cm071003e]
Sequential Self-Organization of Silver(I) Layered Materials with Strong SHG by J Aggregation and Intercalation of Organic Nonlinear Optical Chromophores through Mechanochemical Synthesis
E. CariatiPrimo
;R. MacchiSecondo
;D. Roberto;R. Ugo;A. SironiUltimo
2007
Abstract
The inorganic-organic hybrid layered material of stoichiometry [DAMS+][Ag5I6-], characterized by a strong SHG activity, has been prepared mechanochemically by room-temperature ball-milling a mixture of AgI and [DAMS+][I-], eventually followed by a moderate heating. By means of electronic absorption spectra, XRPD, and second harmonic generation (SHG) experiments we proved that the intralayer ordering of the [DAMS+] nonlinear optical chromophores into J-aggregates precedes the interlayer one, on the whole producing, by a sequential process, the "macropolarity" responsible for the strong SHG. The mechanochemical approach was shown to be of general use, as it was successfully applied to the synthesis of the analogous [DAMS+][Cu5I6-], [DAZOP+][Ag5I6-], and [DAES+][Ag5I6-] materials.Pubblicazioni consigliate
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