The solid-state structures for two complexes, 7 and 8, are reported. Complex 7 was prepared by treating Ru(OAc)(2)(Binap) with two equivalents of HBArF in toluene solution, and represents only the second solid-state structure of a Binap, complex, in which the Binap is a 6e donor to the Ru(II). The bonding is maintained in solution as shown via C-13 NMR studies. The unusual cation 8, as an SbF6- salt, arises from prolonged reaction of Ru(OAc)(2)(Binap) with wet HBF4 (and, subsequently, added HSbF6) in 1,2-dichloroethane.

Structural studies on novel Ru(II)-Binap complexes / T.J. GELDBACH, P.S. PREGOSIN, S. RIZZATO, A. ALBINATI. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - 359:3(2006), pp. 962-969.

Structural studies on novel Ru(II)-Binap complexes

S. RIZZATO
Penultimo
;
A. ALBINATI
Ultimo
2006

Abstract

The solid-state structures for two complexes, 7 and 8, are reported. Complex 7 was prepared by treating Ru(OAc)(2)(Binap) with two equivalents of HBArF in toluene solution, and represents only the second solid-state structure of a Binap, complex, in which the Binap is a 6e donor to the Ru(II). The bonding is maintained in solution as shown via C-13 NMR studies. The unusual cation 8, as an SbF6- salt, arises from prolonged reaction of Ru(OAc)(2)(Binap) with wet HBF4 (and, subsequently, added HSbF6) in 1,2-dichloroethane.
X-ray crystal structures ; ruthenium complexes ; Binap
Settore CHIM/03 - Chimica Generale e Inorganica
2006
Article (author)
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/32136
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 10
  • ???jsp.display-item.citation.isi??? 8
social impact