We compare the adsorption energies calculated by Norskov et al. with data derived from experimental values; except for Ni and Co, which absorb hydrogen strongly, there is a linear relation. We discuss the model proposed by these authors in the light of extensive previous work and of experimental data and find it overly simplistic.
Comment on "Trends in the exchange current for hydrogen evolution" [J. Electrochem. Soc., 152, J23 (2005)] / W. Schmickler, S. Trasatti. - In: JOURNAL OF THE ELECTROCHEMICAL SOCIETY. - ISSN 0013-4651. - 153:12(2006), pp. L31-L32.
Comment on "Trends in the exchange current for hydrogen evolution" [J. Electrochem. Soc., 152, J23 (2005)]
S. Trasatti
2006
Abstract
We compare the adsorption energies calculated by Norskov et al. with data derived from experimental values; except for Ni and Co, which absorb hydrogen strongly, there is a linear relation. We discuss the model proposed by these authors in the light of extensive previous work and of experimental data and find it overly simplistic.File in questo prodotto:
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