Pt{(S,S)-bdpp}(R)I (bdpp= 2,4-bis(diphenylphosphino)pentane; R= Me,Ph, Bz, 2-Tioph) complexes were formed in alkyl/aryl ligand - iodide ligand-exchange reactions by reacting the corresponding Pt{(S,S)-bdpp}R-2 complexes with methyl iodide. The Pt{(S,S)-bdpp}(Me)I complex was isolated and fully characterised. The influence of the X ligand on the platinum-bdpp chelate conformation was investigated in Pt{(S,S)-bdpp}(X)I(X= I, SnCl3, Me) complex series by means of X-ray crystallography.
Synthesis of platinum-iodo-alkyl/aryl complexes in ligand-exchange reactions: Determination of the structure of Pt{(S,S)-bdpp}(X)I complexes (X= Me, I) by X-ray crystallography / L. JANOSI, L. KOLLAR, P. MACCHI, A. SIRONI. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 691:12(2006), pp. 2846-2852.
Synthesis of platinum-iodo-alkyl/aryl complexes in ligand-exchange reactions: Determination of the structure of Pt{(S,S)-bdpp}(X)I complexes (X= Me, I) by X-ray crystallography
P. MACCHIPenultimo
;A. SIRONIUltimo
2006
Abstract
Pt{(S,S)-bdpp}(R)I (bdpp= 2,4-bis(diphenylphosphino)pentane; R= Me,Ph, Bz, 2-Tioph) complexes were formed in alkyl/aryl ligand - iodide ligand-exchange reactions by reacting the corresponding Pt{(S,S)-bdpp}R-2 complexes with methyl iodide. The Pt{(S,S)-bdpp}(Me)I complex was isolated and fully characterised. The influence of the X ligand on the platinum-bdpp chelate conformation was investigated in Pt{(S,S)-bdpp}(X)I(X= I, SnCl3, Me) complex series by means of X-ray crystallography.
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