The linear Kedem-Katchalsky phenomenological and practical equations are examined in order to show their different information content and the usefulness of the latter as a starting point for a non-linear treatment. A simplified analytical treatment of a series array of membranes, following the Patlak-Goldstein-Hoffman method, is subsequently compared with the Kedem-Katchalsky treatment and with the pseudo-electrical network approach of Mikulecky, showing that the analytical and network treatments give the same results in several instances. A comparison with the models of epithelial transport proposed by Weinstein and Stephenson indicates that the series array model includes, as a particular case, the results obtained by means of the standing gradient osmotic flow model.
Considerations on different thermodynamic models for mass transport across membranes / G. Monticelli, F. Celentano. - In: JOURNAL OF MEMBRANE SCIENCE. - ISSN 0376-7388. - 16:C(1983), pp. 109-120. [10.1016/S0376-7388(00)81303-4]
Considerations on different thermodynamic models for mass transport across membranes
G. MonticelliPrimo
;
1983
Abstract
The linear Kedem-Katchalsky phenomenological and practical equations are examined in order to show their different information content and the usefulness of the latter as a starting point for a non-linear treatment. A simplified analytical treatment of a series array of membranes, following the Patlak-Goldstein-Hoffman method, is subsequently compared with the Kedem-Katchalsky treatment and with the pseudo-electrical network approach of Mikulecky, showing that the analytical and network treatments give the same results in several instances. A comparison with the models of epithelial transport proposed by Weinstein and Stephenson indicates that the series array model includes, as a particular case, the results obtained by means of the standing gradient osmotic flow model.Pubblicazioni consigliate
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