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|Title: ||Poly(methylhydrosiloxane)-supported chiral imidazolinones: new versatile, highly efficient and recyclable organocatalysts for stereoselective Diels-Alder cycloaddition reactions|
|Authors: ||BENAGLIA, MAURIZIO|
|Abstract: ||Poly(methylhydrosiloxane) (PMHS) supported organic catalysts promoted the Diels–Alder reaction of dienes with α,β-unsaturated aldehydes, also in pure water, in yields and enantiomeric excesses comparable to those observed with the non-supported catalysts (up to 93% ee). Recycling of the catalysts was performed with no loss of enantioselectivity for at least five reaction cycles.|
|MIUR subjects: ||CHIM/06 - Chimica Organica|
|Publication date: ||2012|
|Digital Object Identifier (DOI): ||10.1039/C2CC17919A|
|Citation: ||Poly(methylhydrosiloxane)-supported chiral imidazolinones: new versatile, highly efficient and recyclable organocatalysts for stereoselective Diels-Alder cycloaddition reactions / S. Guizzetti, M. Benaglia, J.S. Siegel. - In: Chemical communications. - ISSN 1359-7345. - ISSN 1364-548X. - 48:26(2012), pp. 3188-3190.|
|ISI identifier: ||000300874700012|
|Scopus identifier: ||84857706241|
|Type: ||Article (author)|
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