The bidentate sandwich ligand [Fe(η5-C5H4-1-C5H4N)2] has been prepared, structurally characterized and employed in the preparation of the novel supramolecular heterobimetallic metalla-macrocycles [Fe(η5-C5H4-1-C5H4N)2]Ag2(NO3)2·1.5H2O, [Fe(η5-C5H4-1-C5H4N)2]Cu2(CH3COO)4·3H2O and [Fe(η5-C5H4-1-C5H4N)2]Zn2Cl4.
Novel hetero-bimetallic metalla-macrocycles based on the bis-1-pyridyl ferrocene [Fe(η5-C5H4-1-C5H4N)2] ligand. Design, synthesis and structural characterization of the complexes [Fe(η5-C5H4-1-C5H4N)2](Agi)22+/(Cuii)24+/(Znii)24+ / D. Braga, M. Polito, M. Bracaccini, D. D'Addario, E. Tagliavini, D.M. Proserpio, F. Grepioni. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 2002:10(2002), pp. 1080-1081.
Novel hetero-bimetallic metalla-macrocycles based on the bis-1-pyridyl ferrocene [Fe(η5-C5H4-1-C5H4N)2] ligand. Design, synthesis and structural characterization of the complexes [Fe(η5-C5H4-1-C5H4N)2](Agi)22+/(Cuii)24+/(Znii)24+
D.M. ProserpioPenultimo
;
2002
Abstract
The bidentate sandwich ligand [Fe(η5-C5H4-1-C5H4N)2] has been prepared, structurally characterized and employed in the preparation of the novel supramolecular heterobimetallic metalla-macrocycles [Fe(η5-C5H4-1-C5H4N)2]Ag2(NO3)2·1.5H2O, [Fe(η5-C5H4-1-C5H4N)2]Cu2(CH3COO)4·3H2O and [Fe(η5-C5H4-1-C5H4N)2]Zn2Cl4.
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