This report details a conceptual approach to the use of bifunctional complexes for carrying ion pair reagents, such as lithium alkyls or others. This study led to the first crystallographic characterization of organometallic [Mn(Schiff base)RLi(DME)] compounds (R = CH3, 2; R = Ph, 3; R = Mes (=2,4,6-Me(3)C(6)H(2)), 3). The importance of these complexes lies in, the electronic and steric modification, of lithium alkyl chemistry. Preliminary studies with PhCHO and PhCN show how complexes 2-4 react in a bifunctional fashion with organic substrates.
Bifunctional Carriers of Polar Organometallics Using Transition-Metal-Schiff Base Complexes: A Very Easy Access to Manganese(II)-Carbon Functionalities / E. Gallo, E. Solari, C. Floriani, A. Chiesi Villa, C. Rizzoli. - In: ORGANOMETALLICS. - ISSN 0276-7333. - 14:5(1995), pp. 2156-2158. [10.1021/om00005a011]
Bifunctional Carriers of Polar Organometallics Using Transition-Metal-Schiff Base Complexes: A Very Easy Access to Manganese(II)-Carbon Functionalities
E. GalloPrimo
;
1995
Abstract
This report details a conceptual approach to the use of bifunctional complexes for carrying ion pair reagents, such as lithium alkyls or others. This study led to the first crystallographic characterization of organometallic [Mn(Schiff base)RLi(DME)] compounds (R = CH3, 2; R = Ph, 3; R = Mes (=2,4,6-Me(3)C(6)H(2)), 3). The importance of these complexes lies in, the electronic and steric modification, of lithium alkyl chemistry. Preliminary studies with PhCHO and PhCN show how complexes 2-4 react in a bifunctional fashion with organic substrates.
| File | Dimensione | Formato | |
|---|---|---|---|
|
06) MnCH3Li1.pdf
accesso riservato
Tipologia:
Publisher's version/PDF
Dimensione
302.04 kB
Formato
Adobe PDF
|
302.04 kB | Adobe PDF | Visualizza/Apri Richiedi una copia |
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
