The aerial oxidation of ethane-1,2-diol in the presence of copper metal and pyridine (py) at room temperature and atmospheric pressure produces [Cu(py)2(HCO2)2].H2O and [Cu2(py)4(OCH2CO2)2].(CH2OH)2; the structure of the latter has been fully elucidated by an X-ray study.
THE OXIDATION OF ETHANE-1,2-DIOL RESULTING FROM MOLECULAR-OXYGEN ACTIVATION BY COPPER - FORMATION OF AN OXOETHANOATE COMPLEX PRECEDES CARBON-CARBON BOND-CLEAVAGE / M. LANFRANCHI, L. PRATI, M. ROSSI, A. TIRIPICCHIO. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :22(1993), pp. 1698-1699. [10.1039/c39930001698]
THE OXIDATION OF ETHANE-1,2-DIOL RESULTING FROM MOLECULAR-OXYGEN ACTIVATION BY COPPER - FORMATION OF AN OXOETHANOATE COMPLEX PRECEDES CARBON-CARBON BOND-CLEAVAGE
L. PratiSecondo
;M. RossiPenultimo
;
1993
Abstract
The aerial oxidation of ethane-1,2-diol in the presence of copper metal and pyridine (py) at room temperature and atmospheric pressure produces [Cu(py)2(HCO2)2].H2O and [Cu2(py)4(OCH2CO2)2].(CH2OH)2; the structure of the latter has been fully elucidated by an X-ray study.
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
