The reactions of amines and related species with molecular oxygen bound to a transition metal centre, are reviewed briefly. New results on the reactions of Pt(PPh3)2O2 with amine derivatives such as formanilides and imides are reported; from these reactions new amidohydroperoxoplatinum(II) complexes have been isolated. The related reaction of Pt(PPh3)2O2 with phenol is also described. A general mechanism for these deprotonation reactions is discussed.
REACTIONS OF AMINES AND RELATED SPECIES WITH TRANSITION-METAL PEROXO COMPLEXES / S. CENINI, F. PORTA, M. PIZZOTTI. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 296:1-2(1985), pp. 291-300.
REACTIONS OF AMINES AND RELATED SPECIES WITH TRANSITION-METAL PEROXO COMPLEXES
S. CENINI;F. PORTA;M. PIZZOTTI
1985
Abstract
The reactions of amines and related species with molecular oxygen bound to a transition metal centre, are reviewed briefly. New results on the reactions of Pt(PPh3)2O2 with amine derivatives such as formanilides and imides are reported; from these reactions new amidohydroperoxoplatinum(II) complexes have been isolated. The related reaction of Pt(PPh3)2O2 with phenol is also described. A general mechanism for these deprotonation reactions is discussed.
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