The [Rh13(CO)24H5-n]n- (n = 2 or 3) anions have been isolated from the reaction of the [Rh12(CO) 30]2- dianion with hydrogen; they are structurally related to a close hexagonal packing of rhodium atoms having mean distances of 2.81 Å.
Hexagonal close packing of metal atoms in the new polynuclear anions [Rh13(CO)24H5-n]n- (n=2 or 3); x-ray structure of [(Ph3P)2N]2[Rh13(CO)24H3]. / V.G.Albano, A.Ceriotti, P.Chini, G.Ciani, S.Martinengo, W.M.Anker. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :20(1975), pp. 859-860.
Hexagonal close packing of metal atoms in the new polynuclear anions [Rh13(CO)24H5-n]n- (n=2 or 3); x-ray structure of [(Ph3P)2N]2[Rh13(CO)24H3].
A.CeriottiSecondo
;
1975
Abstract
The [Rh13(CO)24H5-n]n- (n = 2 or 3) anions have been isolated from the reaction of the [Rh12(CO) 30]2- dianion with hydrogen; they are structurally related to a close hexagonal packing of rhodium atoms having mean distances of 2.81 Å.
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