[IrH5(PEt3)2] reacts with [(PR3)2Rh(μ2-Cl)2(PR3)2] (PR3 = PEt3 or 2 PR3 = Ph2PCH2CH2PPh2) to give the hydrido-bridged binuclear species [(PR3)2Rh(μ2-H)(μ2-Cl)IrH2(PR3)2] which show catalytic activity in alkene hydrogenation.
Some new rhodium(I)-iridium(III) complexes with bridging hydride and chloride ligands / H. Lehner, A. Musco, L. M. Venanzi, A. Albinati. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 213:2(1981), pp. C46-C48.
Some new rhodium(I)-iridium(III) complexes with bridging hydride and chloride ligands
A. AlbinatiUltimo
1981
Abstract
[IrH5(PEt3)2] reacts with [(PR3)2Rh(μ2-Cl)2(PR3)2] (PR3 = PEt3 or 2 PR3 = Ph2PCH2CH2PPh2) to give the hydrido-bridged binuclear species [(PR3)2Rh(μ2-H)(μ2-Cl)IrH2(PR3)2] which show catalytic activity in alkene hydrogenation.
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