The synthesis and properties of palladium(II) and platinum(II) complexes with quadridentate Schiff bases derived from the condensation of salicylaldehyde and (R)-1,2-diamines are described. The ligand conformation of the platinum(II) complexes is discussed on the basis of the circular dichroism and the 1H n.m.r. spectra. The anomalous patterns of the circular dichroism spectra of palladium(II) derivatives are also reported.
Optically active complexes of Schiff bases. Part 6. Palladium(II) and platinum(II) complexes with quadridentate Schiff bases of salicylaldehyde / E. Cesarotti, A. Pasini, R. Ugo. - In: JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS. - ISSN 0300-9246. - 1981:11(1981), pp. 2147-2152.
Optically active complexes of Schiff bases. Part 6. Palladium(II) and platinum(II) complexes with quadridentate Schiff bases of salicylaldehyde
E. CesarottiPrimo
;A. PasiniSecondo
;
1981
Abstract
The synthesis and properties of palladium(II) and platinum(II) complexes with quadridentate Schiff bases derived from the condensation of salicylaldehyde and (R)-1,2-diamines are described. The ligand conformation of the platinum(II) complexes is discussed on the basis of the circular dichroism and the 1H n.m.r. spectra. The anomalous patterns of the circular dichroism spectra of palladium(II) derivatives are also reported.
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