The synthesis of poly(methacrylamido-thioetheramine)s by thermal polyaddition of 2,2'-alkylenediiminodiethanethiols to 1,4-bismethacryloylpiperazine is reported. These products show less pronounced hydrolytic behavior in acidic aqueous solution than the corresponding poly(acrylamido-thioetheramine)s. They were characterized by viscometric measurements, elemental analyses, Fourier transform infrared spectrophotometer, nuclear magnetic resonance and differential scanning calorimeter.
TERTIARY AMINO POLYMERS BY POLYADDITION OF 2,2'-ALKYLENEDIIMINODIETHANETHIOLS TO 1,4-BISMETHACRYOYLPIPERAZINE / E. RANUCCI, Bignotti, F, Dancelli, E., Ferruti, P.. - In: POLYMER JOURNAL. - ISSN 0032-3896. - 25:6(1993), pp. 625-631.
TERTIARY AMINO POLYMERS BY POLYADDITION OF 2,2'-ALKYLENEDIIMINODIETHANETHIOLS TO 1,4-BISMETHACRYOYLPIPERAZINE
E. RANUCCIPrimo
;
1993
Abstract
The synthesis of poly(methacrylamido-thioetheramine)s by thermal polyaddition of 2,2'-alkylenediiminodiethanethiols to 1,4-bismethacryloylpiperazine is reported. These products show less pronounced hydrolytic behavior in acidic aqueous solution than the corresponding poly(acrylamido-thioetheramine)s. They were characterized by viscometric measurements, elemental analyses, Fourier transform infrared spectrophotometer, nuclear magnetic resonance and differential scanning calorimeter.
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