The use of water instead of benzene as the solvent can strongly influence the stereoselectivity and the rate of Diels-Alder reactions of 1,4-naphthoquinone derivatives with different dienes. Enantiomeric excess (e.e.) up to 38% is reached in the presence of a catalytic amount of bovine serum albumin.
CHANGES OF STEREOSELECTIVITY AND RATE IN DIELS-ALDER REACTIONS BY HYDROPHOBIC SOLVENT EFFECTS AND BY BOVINE SERUM-ALBUMIN / S. COLONNA, A. MANFREDI, R. ANNUNZIATA. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 29:27(1988), pp. 3347-3350.
CHANGES OF STEREOSELECTIVITY AND RATE IN DIELS-ALDER REACTIONS BY HYDROPHOBIC SOLVENT EFFECTS AND BY BOVINE SERUM-ALBUMIN
A. MANFREDISecondo
;R. ANNUNZIATAUltimo
1988
Abstract
The use of water instead of benzene as the solvent can strongly influence the stereoselectivity and the rate of Diels-Alder reactions of 1,4-naphthoquinone derivatives with different dienes. Enantiomeric excess (e.e.) up to 38% is reached in the presence of a catalytic amount of bovine serum albumin.
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
