Dihydroquinidine acetate promoted osmylation of acetals of E-α,β- unsaturated aldehydes occurs with up to 40:1 stereoselection to afford the corresponding protected syn-α,β -dihydroxy aldehydes.
HIGHLY STEREOSELECTIVE SYNTHESIS OF OPTICALLY-ACTIVE MASKED SYN-ALPHA-BETA-DIHYDROXY ALDEHYDES / R. ANNUNZIATA, M. CINQUINI, F. COZZI, L. RAIMONDI, S. STEFANELLI. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 28:27(1987), pp. 3139-3142.
HIGHLY STEREOSELECTIVE SYNTHESIS OF OPTICALLY-ACTIVE MASKED SYN-ALPHA-BETA-DIHYDROXY ALDEHYDES
R. ANNUNZIATAPrimo
;M. CINQUINISecondo
;F. COZZI;L. RAIMONDIPenultimo
;
1987
Abstract
Dihydroquinidine acetate promoted osmylation of acetals of E-α,β- unsaturated aldehydes occurs with up to 40:1 stereoselection to afford the corresponding protected syn-α,β -dihydroxy aldehydes.
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