Pyrrolidines 5a-b, and piperidines 10a,b and 15, were synthesised by Grignard reaction on a glycosylamine, easily obtained from the parent sugar and a primary amine, followed by cyclization with triflic anhydride.
SYNTHESIS OF AZASUGARS BY GRIGNARD REACTION ON GLYCOSYLAMINES / L. CIPOLLA, L. LAY, F. NICOTRA, C. PANGRAZIO, L. PANZA. - In: TETRAHEDRON. - ISSN 0040-4020. - 51:16(1995), pp. 4679-4690.
SYNTHESIS OF AZASUGARS BY GRIGNARD REACTION ON GLYCOSYLAMINES
L. LAYSecondo
;
1995
Abstract
Pyrrolidines 5a-b, and piperidines 10a,b and 15, were synthesised by Grignard reaction on a glycosylamine, easily obtained from the parent sugar and a primary amine, followed by cyclization with triflic anhydride.
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