An X-ray crystallographic study has shown that the novel dianion [Rh 14(CO)26]2-, which has been isolated from the products obtained in the pyrolysis of Na2-[Rh13H 3(CO)24] or of mixtures of Rh4(CO)12 and NaOH in propan-2-ol at reflux, contains a metal atom cluster, with one interstitial metal atom, which can be described as intermediate between a compact close-packed and a body-centred cubic array.
Synthesis and x-ray crystal structure of the novel high nuclearity rhodium-cluster dianion [Rh14(μ-CO)15(CO) 11]2 / S. Martinengo, G. Ciani, A. Sironi. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :23(1980), pp. 1140-1141.
Synthesis and x-ray crystal structure of the novel high nuclearity rhodium-cluster dianion [Rh14(μ-CO)15(CO) 11]2
G. CianiSecondo
;A. SironiUltimo
1980
Abstract
An X-ray crystallographic study has shown that the novel dianion [Rh 14(CO)26]2-, which has been isolated from the products obtained in the pyrolysis of Na2-[Rh13H 3(CO)24] or of mixtures of Rh4(CO)12 and NaOH in propan-2-ol at reflux, contains a metal atom cluster, with one interstitial metal atom, which can be described as intermediate between a compact close-packed and a body-centred cubic array.
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