The unsaturated tetrahedral cluster {[Re-4(mu(3)-H)(4)(CO)(12)] easily added halide ions giving [Re(4)H(4)X(CO)(12)](-) anions, which in the presence of even poor donor species underwent fragmentation to unsaturated triangular cluster anions.}
Spectroscopic titration of {[Re-4(mu(3)-H)(4)(CO)(12)] with chloride ions. An electron-precise tetranuclear cluster as intermediate in the transformation of a tetranuclear unsaturated cluster into trinuclear unsaturated anions} / T. Beringhelli, G. D'Alfonso, M. Garavaglia. - In: JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS. - ISSN 0300-9246. - :8(1996), pp. 1771-1773.
Spectroscopic titration of {[Re-4(mu(3)-H)(4)(CO)(12)] with chloride ions. An electron-precise tetranuclear cluster as intermediate in the transformation of a tetranuclear unsaturated cluster into trinuclear unsaturated anions}
T. BeringhelliPrimo
;G. D'AlfonsoSecondo
;
1996
Abstract
The unsaturated tetrahedral cluster {[Re-4(mu(3)-H)(4)(CO)(12)] easily added halide ions giving [Re(4)H(4)X(CO)(12)](-) anions, which in the presence of even poor donor species underwent fragmentation to unsaturated triangular cluster anions.}Pubblicazioni consigliate
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