(22R,23R)- and (22S,23S)-2α,3α,22,23-Tetrahydroxy-B-homo-7-oxa- 5α-ergostan-6-one, two physiologically active brassino steroids, have been synthesized via key intermediate brassicasterol obtained in a very simple way by reduction with lithium dissolved in ethylamine of the 1,4-cycloadduct of ergosterol and 4-phenyl-1,2,4-triazoline-3,5-dione.
A new synthesis of brassino steroids: Plant growth promoting steroids / M. Anastasia, P. Ciuffreda, A. Fiecchi. - In: JOURNAL OF THE CHEMICAL SOCIETY. PERKIN TRANSACTIONS. I. - ISSN 0300-922X. - (1983), pp. 379-382.
A new synthesis of brassino steroids: Plant growth promoting steroids
M. AnastasiaPrimo
;P. CiuffredaSecondo
;
1983
Abstract
(22R,23R)- and (22S,23S)-2α,3α,22,23-Tetrahydroxy-B-homo-7-oxa- 5α-ergostan-6-one, two physiologically active brassino steroids, have been synthesized via key intermediate brassicasterol obtained in a very simple way by reduction with lithium dissolved in ethylamine of the 1,4-cycloadduct of ergosterol and 4-phenyl-1,2,4-triazoline-3,5-dione.File in questo prodotto:
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