The anion [Rh6(CO)14(CP3H5]-, obtained by reaction of [Rh6(CO)15]2- with allyl chloride, contains an octahedral rhodium cluster with a mean metalmetal distance of 2.753 Å. The structure of the carbonyl resembles that of Rh6(CO)16, with the two terminal CO groups of one metal atom replaced by a π-bonded allyl group. © 1980.
Synthesis and structural characterization of the anion [Rh6(CO)14(η3-C3H5)] / G. Ciani, A. Sironi, P. Chini, A. Ceriotti, S. Martinengo. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 192:2(1980), pp. C39-C39-C41.
Synthesis and structural characterization of the anion [Rh6(CO)14(η3-C3H5)]
G. CianiPrimo
;A. SironiSecondo
;A. CeriottiPenultimo
;
1980
Abstract
The anion [Rh6(CO)14(CP3H5]-, obtained by reaction of [Rh6(CO)15]2- with allyl chloride, contains an octahedral rhodium cluster with a mean metalmetal distance of 2.753 Å. The structure of the carbonyl resembles that of Rh6(CO)16, with the two terminal CO groups of one metal atom replaced by a π-bonded allyl group. © 1980.
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