The anion [Rh10(CO)21]2-, obtained by reaction of [Rh9(CO)19]3- with the [Rh(CO) 2(NCMe)2]+ cation, contains a novel decanuclear metallic skeleton which is a fragment of hexagonal close-packed lattice formed by three superimposed layers (3/4/3 metals), with two octahedral and two tetrahedral condensed units as confirmed by X-ray crystallography.
Synthesis and x-ray crystal structure of the cluster dianion, [Rh 10(CO)21]2-, containing a new compact array of metal atoms / S. Martinengo, G. Ciani, A. Sironi. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :16(1986), pp. 1282-1283.
Synthesis and x-ray crystal structure of the cluster dianion, [Rh 10(CO)21]2-, containing a new compact array of metal atoms
G. CianiSecondo
;A. SironiUltimo
1986
Abstract
The anion [Rh10(CO)21]2-, obtained by reaction of [Rh9(CO)19]3- with the [Rh(CO) 2(NCMe)2]+ cation, contains a novel decanuclear metallic skeleton which is a fragment of hexagonal close-packed lattice formed by three superimposed layers (3/4/3 metals), with two octahedral and two tetrahedral condensed units as confirmed by X-ray crystallography.
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