Partial fragmentation of [Re7C(CO)21]3-, by reaction with I2 in MeCN under CO atmosphere, affords the title compound, which contains a carbide atom at the centre of a tetrahedrally distorted square of rhenium atoms.
A new metallic environment for carbon in a carbido metal cluster: X-ray crystal structure of the anion [Re4C(CO)15I] / T. Beringhelli, G. Ciani, G. D'Alfonso, A. Sironi, M. Freni. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :14(1985), pp. 978-979.
A new metallic environment for carbon in a carbido metal cluster: X-ray crystal structure of the anion [Re4C(CO)15I]
T. BeringhelliPrimo
;G. CianiSecondo
;G. D'Alfonso;A. SironiPenultimo
;
1985
Abstract
Partial fragmentation of [Re7C(CO)21]3-, by reaction with I2 in MeCN under CO atmosphere, affords the title compound, which contains a carbide atom at the centre of a tetrahedrally distorted square of rhenium atoms.
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