A specific and efficient synthesis of (±)-dihydrocorynantheol (1) is reported. Starting with the easily accessible imine (3), ring D was built via stereoselective reaction with the lactone (4a), thus providing the complete carbon skeleton of (1); subsequent elaboration gave the desired alkaloid (1).
A specific and efficient synthesis of (±)-dihydrocorynantheol / B. Danieli, G. Lesma, G. Palmisano, S. Tollari. - In: JOURNAL OF THE CHEMICAL SOCIETY. PERKIN TRANSACTIONS. I. - ISSN 0300-922X. - :0(1984), pp. 1237-1240. [10.1039/P19840001237]
A specific and efficient synthesis of (±)-dihydrocorynantheol
B. DanieliPrimo
;G. LesmaSecondo
;
1984
Abstract
A specific and efficient synthesis of (±)-dihydrocorynantheol (1) is reported. Starting with the easily accessible imine (3), ring D was built via stereoselective reaction with the lactone (4a), thus providing the complete carbon skeleton of (1); subsequent elaboration gave the desired alkaloid (1).
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