Hydroboration of 5α-cholest-8-ene, 5α, 14β-cholest-8-ene and 5α, 14β-cholest-7-ene provides a simple route to oxygenated steroids with 14β- and 8α, 14β- unnatural stereochemistry.
STEREOCHEMICAL COURSE OF THE HYDROBORATION OF HIGHLY HINDERED STEROIDAL OLEFINS - A READY SYNTHESIS OF 14-BETA-STEROIDS AND 8-ALPHA,14-BETA-STEROIDS / M. ANASTASIA, P. ALLEVI, A. FIECCHI, A. OLEOTTI, A. SCALA. - In: STEROIDS. - ISSN 0039-128X. - 47:2-3(1986), pp. 131-141.
STEREOCHEMICAL COURSE OF THE HYDROBORATION OF HIGHLY HINDERED STEROIDAL OLEFINS - A READY SYNTHESIS OF 14-BETA-STEROIDS AND 8-ALPHA,14-BETA-STEROIDS
M. ANASTASIAPrimo
;P. ALLEVISecondo
;
1986
Abstract
Hydroboration of 5α-cholest-8-ene, 5α, 14β-cholest-8-ene and 5α, 14β-cholest-7-ene provides a simple route to oxygenated steroids with 14β- and 8α, 14β- unnatural stereochemistry.
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