A new chemoenzymatic synthesis of both enantiomers of mevalonolactone 1 starting from the Pseudomonas fluorescens lipase-catalyzed resolution of racemic 2-(3-methyl-2-butenyl)-oxiranemethanol 2 is reported.
A New Synthesis of (R)- and (S)-Mevalonolactone from the Enzymatic Resolution of (R,S)-2-(3-Methyl-2-butenyl)-oxiranemethanol / P. Ferraboschi, P. Grisenti, S. Casati, E. Santaniello. - In: SYNLETT. - ISSN 0936-5214. - :9(1994), pp. 754-756.
A New Synthesis of (R)- and (S)-Mevalonolactone from the Enzymatic Resolution of (R,S)-2-(3-Methyl-2-butenyl)-oxiranemethanol
P. FerraboschiPrimo
;S. CasatiPenultimo
;E. SantanielloUltimo
1994
Abstract
A new chemoenzymatic synthesis of both enantiomers of mevalonolactone 1 starting from the Pseudomonas fluorescens lipase-catalyzed resolution of racemic 2-(3-methyl-2-butenyl)-oxiranemethanol 2 is reported.
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