Both vinyl and β-halogenoethyl sulphilimines can be obtained in optically active form via kinetic resolution in the elimination reaction of the latter promoted by chiral bases, with enantiomeric excesses of up to 73%; the influence of the resolving agent and of the leaving group on the chiral discrimination has also been examined.

Synthesis of optically active sulphilimines via chiral discrimination / R. Annunziata, M. Cinquini, S. Colonna, F. Cozzi. - In: JOURNAL OF THE CHEMICAL SOCIETY. PERKIN TRANSACTIONS. I. - ISSN 0300-922X. - :0(1981), pp. 3118-3119.

Synthesis of optically active sulphilimines via chiral discrimination

R. Annunziata
Primo
;
M. Cinquini
Secondo
;
S. Colonna
Penultimo
;
F. Cozzi
Ultimo
1981

Abstract

Both vinyl and β-halogenoethyl sulphilimines can be obtained in optically active form via kinetic resolution in the elimination reaction of the latter promoted by chiral bases, with enantiomeric excesses of up to 73%; the influence of the resolving agent and of the leaving group on the chiral discrimination has also been examined.
Settore CHIM/06 - Chimica Organica
1981
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/182343
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